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I'm not a native speaker, so frequently I don't know underlying semantic subtleties of synonyms; what connotations they bear, which may be antiquated or very official, which are specific to given region or group and such.
Currently, I'm struggling with:
engagement / betrothal,
betrothed / affianced / engaged / to be married
betrothed / a wife-to-be / husband-to-be / fiancée / fiancé