The most effective exercises for the upper part, which you should try.
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If you want to work the pecs. We have the classic and the king; Bench press.
Pull-ups: It is an exercise with our own body weight that allows us to work the back, and at the same time it is multi-joint that also works other parts of our muscles.
If you can't do pull-ups, you can do Reverse Row, until you're strong enough to do good pull-ups.
Military Press: For our shoulders, you can do it standing, sitting, kneeling with barbell dumbbells and however you feel comfortable. the important thing is that you do it right.
For the biceps we have the barbell curl and you can also do it with dumbbells.
And finally to finish this list we have. the French Press: It will work our triceps, ideal for a good stimulation of our triceps.